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81.
通过溶液聚合法制备了具有空心结构的聚氰基丙烯酸乙酯纳米纤维,纤维直径为50~100 nm.研究了3种溶液体系对形成聚氰基丙烯酸乙酯纳米纤维形貌与直径的影响,并探讨了其形成机理.通过调控溶液体系内外环境可得到不同形貌的聚合物纤维,且纤维表面表现出疏水性质.该方法适用于平整且具有粗糙结构的表面.所形成的聚氰基丙烯酸乙酯纳米纤维涂层可用于基底的疏水改性. 相似文献
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Qing-Qing Guan Xiao-Dian Huang Yan-Hua Zeng Chao-Hai Wei Ping Ning Gu Jun-Jie Xin-Sheng Chai 《Chemical Papers》2015,69(5):662-667
This paper reports a headspace analysis technique for the determination of products, i.e., cyclohexanone (CE) and cyclohexanol (CL), of phenol hydrogenation in a supercritical water reaction system (SWRS) with water removal by hydrate formation. An addition of anhydrous calcium chloride leads to water absorption resulting in crystal water; thus, the samples can be quantitatively measured without the influence of water. After achieving equilibrium at 150°C and maintaining it for 5 min, the obtained results showed a relative standard deviation of less than 5.3% and the recovery ranged from 93% to 104%. The presented method is simple and accurate for the analysis of CL, CE and phenol in samples from phenol conversion in SWRS. 相似文献
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Fei Wang Xueqian Wang Ping Ning Xuli Jing Yixing Ma Ping Wang Wei Chen 《Adsorption》2015,21(5):401-408
A series of adsorbents were studied for removal efficiency of carbon disulfide (CS2) under micro-oxygen conditions. It was found that activated carbon modified by Cu and cobalt sulfonated phthalocyanine (CoSPc) denoted as ACCu–CoSPc showed significantly enhanced adsorption ability. Reaction temperature was found to be a key factor for adsorption, and 20 °C seems to be optimal for CS2 removal. Samples were analyzed by N2-BET, XRD, XPS, SEM–EDS and CO2-TPD. The characterization results demonstrated that large quantities of SO4 2? anions were formed and adsorbed in the reaction process. SO2, CS2 and COS were detected in the effluent gas generated from the temperature programmed desorption of ACCu–CoSPc–CS2. Therefore, it can be concluded that ACCu–CoSPc most likely acted as a catalyst in the adsorption/oxidation process on the surface of the impregnated sample. The generated sulfide and sulfur oxide can cover the active sites of adsorbents, resulting in pronounced reduction of adsorbent activity. Finally, the exhausted ACCu–CoSPc can be regenerated by thermal desorption. 相似文献
87.
Cationic Cobalt(III)‐Catalyzed Aryl and Alkenyl CH Amidation: A Mild Protocol for the Modification of Purine Derivatives 下载免费PDF全文
Yujie Liang Yu‐Feng Liang Conghui Tang Yizhi Yuan Prof. Dr. Ning Jiao 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(46):16395-16399
A cationic cobalt(III)‐catalyzed direct C?H amidation of unactivated (hetero)arenes and alkenes by using 1,4,2‐dioxazol‐5‐ones as the amidating reagent has been developed. This transformation proceeds efficiently under external oxidant‐free conditions with a broad substrate scope. Moreover, 6‐arylpurine compounds, which often exhibit high potency in antimycobacterial, cytostatic, and anti‐HCV activities, can be smoothly amidated, thus offering a mild protocol for their late stage functionalization. 相似文献
88.
Haixiong Hu Zhongai Hu Xiaoying Ren Yuying Yang Ruibing Qiang Ning An Hongying Wu 《中国化学》2015,33(2):199-206
The reduced graphene oxide (RGO)/bisphenol A (BPA) composites were prepared by an adsorption‐reduction method. The composites are characterized by X‐ray diffraction (XRD), UV‐vis, thermogravimetric (TG) analysis, field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM). The results confirm that BPA is adsorbed on the basal plane of RGO by π‐π stacking interaction. Furthermore, the electrochemical behaviors were evaluated by cyclic voltammetry, galvanostatic charge/discharge techniques and electrochemical impedance spectroscopy (EIS). The results show that the RGO/BPA nanocomposites exhibit ultrahigh specific capacitance of 466 F·g?1 at a current density of 1 A·g?1, excellent rate capability (more than 81% retention at 10 A·g?1 relative to 1 A·g?1) and superior cycling stability (90% capacitance decay after 4000 cycles). Consequently, the RGO/BPA nanocomposites can be regarded as promising electrode materials for supercapacitor applications. 相似文献
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90.
芳胺与三光气反应制得芳基异氰酸酯(2a~2n);2a~2n分别对布雷菲德菌素A(3)的7-羟基进行结构修饰,合成了14个新型布雷菲德菌素A氨基甲酸酯类衍生物——7-O-(芳基氨基甲酸酯)-布雷菲德菌素A(4a~4n),其结构经1H NMR,13C NMR和ESI-HR-MS表征。初步的抗肿瘤活性测定结果表明,4i~4k均丧失抑制食管癌细胞株TE-1活性。分子对接研究揭示,引入3后,4的分子空间位阻增大,导致不能与靶位结合,致使抗肿瘤活性丧失。 相似文献